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Ambiphilicity of a mononuclear cobalt(III) superoxo complex

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Bill,  Eckhard
Research Department DeBeer, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Ye,  Shengfa
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences;
Research Group Ye, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Chen, T.-Y., Ho, P.-H., Spyra, C.-J., Meyer, F., Bill, E., Ye, S., et al. (2020). Ambiphilicity of a mononuclear cobalt(III) superoxo complex. Chemical Communications, 56(94), 14821-14824. doi:10.1039/D0CC05337F.


Cite as: http://hdl.handle.net/21.11116/0000-0007-AB03-5
Abstract
Addition of HOTf to a mixture of CoIII(BDPP)(O2˙) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp*2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.