Boron Carbon Nitride Thin Films: From Disordered to Ordered Conjugated Ternary 
Materials

Giusto, Paolo; Arazoe, Hiroki; Cruz, Daniel; Lova, Paola; Heil, Tobias; Aida, Takuzo; Antonietti, Markus

doi:10.1021/jacs.0c10945

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Boron Carbon Nitride Thin Films: From Disordered to Ordered Conjugated Ternary Materials

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Cruz, Daniel
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;
Department of Heterogeneous Reactions, Max-Planck-Institut für Chemische Energiekonversion;

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Citation

Giusto, P., Arazoe, H., Cruz, D., Lova, P., Heil, T., Aida, T., et al. (2020). Boron Carbon Nitride Thin Films: From Disordered to Ordered Conjugated Ternary Materials. Journal of the American Chemical Society, 142(49), 20883-20891. doi:10.1021/jacs.0c10945.

Cite as: https://hdl.handle.net/21.11116/0000-0007-A340-8

Abstract

We present an innovative method for the synthesis of boron carbon nitride thin film materials in a simple furnace setup, using commonly available solid precursors and relatively low temperature compared to previous attempts. The as-prepared structural and optical properties of thin films are tuned via the precursor content, leading to a sp²-conjugated boron nitride–carbon nitride mixed material, instead of the commonly reported boron nitride–graphene phase segregation, with tunable optical properties such as band gap and fluorescence.