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Adhesion and De-adhesion mechanisms at polymer/metal interfaces: Mechanistic understanding based on in situ studies of buried interfaces

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Grundmeier,  Guido
Adhesion and Thin Films, Interface Chemistry and Surface Engineering, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society;
Christian Doppler Laboratory for Metal/Polymer Interfaces, Interface Chemistry and Surface Engineering, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society;

/persons/resource/persons125406

Stratmann,  Martin
Interface Chemistry and Surface Engineering, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society;

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Citation

Grundmeier, G., & Stratmann, M. (2005). Adhesion and De-adhesion mechanisms at polymer/metal interfaces: Mechanistic understanding based on in situ studies of buried interfaces. Annual Review of Materials Research, 35, 571-615. doi:10.1146/annurev.matsci.34.012703.105111.


Cite as: https://hdl.handle.net/21.11116/0000-0008-2E5C-F
Abstract
The review highlights the state-of-the-art research regarding the
application of modem in situ spectroscopic, microscopic, and
electrochemical techniques to improve the understanding of the
interaction of organic molecules with metal surfaces. We also consider
the chemical and electrochemical processes that lead to a de-adhesion of
polymers from metal surfaces. Spectroscopic techniques such as
surface-enhanced infrared or Raman spectroscopy provide molecular
understanding of organic molecules and water at buried metal surfaces.
This information is complementary to adhesion studies by means of atomic
force microscopy and de-adhesion studies of polymer layers from metals
by means of a scanning Kelvin probe. Adhesion and de-adhesion mechanisms
are discussed, especially those involving humid and corrosive
environments, which are the predominant and most important for
metal/polymer composites in engineering applications.