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Journal Article

Deoxygenation of Coordinated Oxaphosphiranes: A New Route to P=C Double‐Bond Systems

MPS-Authors
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Shi,  Lili
Research Department Neese, Max Planck Institute for Bioinorganic Chemistry, Max Planck Society;

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van Gastel,  Maurice
Research Department Lubitz, Max Planck Institute for Bioinorganic Chemistry, Max Planck Society;

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Neese,  Frank
Research Department Neese, Max Planck Institute for Bioinorganic Chemistry, Max Planck Society;

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Citation

Albrecht, C., Shi, L., Marinas Pérez, J., van Gastel, M., Schwieger, S., Neese, F., et al. (2012). Deoxygenation of Coordinated Oxaphosphiranes: A New Route to P=C Double‐Bond Systems. Chemistry – A European Journal, 18(32), 9780-9783. doi:10.1002/chem.201201405.


Cite as: https://hdl.handle.net/21.11116/0000-0007-E4D8-4
Abstract
Phosphaalkenes: Deoxygenation of oxaphosphirane complexes 1 and 2 by using TiIII complexes gave mixtures of E/Z phosphaalkene complexes 3 a, b and 4 a, b. Theoretical calculations of deoxygenation pathways of 1 revealed that the final products are obtained via intermediate 5 providing the final products by reaction with a second [TiCpCl2] unit and C-O bond cleavage (see scheme).