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Mastering extreme size constraints in the clathrate-I borosilicide Cs8B8Si38

MPS-Authors
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Hübner,  Julia-Maria
Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Jung,  Walter
Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Kozelj,  Primož
Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Bobnar,  Matej
Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Cardoso Gil,  Raul
Raul Cardoso, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Burkhardt,  Ulrich
Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Böhme,  Bodo
Bodo Böhme, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Baitinger,  Michael
Michael Baitinger, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Schwarz,  Ulrich
Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Grin,  Yuri
Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Hübner, J.-M., Jung, W., Kozelj, P., Bobnar, M., Cardoso Gil, R., Burkhardt, U., et al. (2021). Mastering extreme size constraints in the clathrate-I borosilicide Cs8B8Si38. Zeitschrift für anorganische und allgemeine Chemie, 647(2-3), 119-125. doi:10.1002/zaac.202000400.


Cite as: https://hdl.handle.net/21.11116/0000-0008-031A-8
Abstract
Cs8B8Si38 is obtained by high-pressure high-temperature synthesis at p=8 GPa and T=1273 K. The new compound (space group Pm (Formula presented.) n; a=10.0312(3) Å) is the third example for a clathrate-I borosilicide after the potassium and rubidium varieties, respectively. The phase slowly deteriorates in air and moisture but is thermally stable up to 1050 K at ambient pressure. [Cs+]8[B–]8[Si0]38 is electronically balanced, diamagnetic, and shows semiconducting behavior. © 2021 The Authors. Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH