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Journal Article

Bioinorganic Reaction Mechanisms: From High‐Valent Iron to Bioorganometallic Chemistry

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Slep,  Leonardo D.
Research Department Wieghardt, Max Planck Institute for Radiation Chemistry, Max Planck Society;

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Neese,  Frank
Research Department Wieghardt, Max Planck Institute for Radiation Chemistry, Max Planck Society;

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Citation

Slep, L. D., & Neese, F. (2003). Bioinorganic Reaction Mechanisms: From High‐Valent Iron to Bioorganometallic Chemistry. Angewandte Chemie International Edition, 42(26), 2942-2945. doi:10.1002/anie.200301649.


Cite as: http://hdl.handle.net/21.11116/0000-0008-109F-3
Abstract
Important aspects of the mechanisms of fundamental bioinorganic reactions have been revealed in recent studies, which have shed light on the structure and properties of high‐valent nonheme Fe centers (left structure) as well as on the biosynthetic formation of the Fe-CN bond in Ni–Fe hydrogenases (right).