Insights into the Chemistry of Transient P‐Chlorophosphanyl Complexes

Özbolat‐Schön, Aysel; Bode, Maren; Schnakenburg, Gregor; Anoop, Anakuthil; van Gastel, Maurice; Neese, Frank; Streubel, Rainer

doi:10.1002/anie.201002885

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Insights into the Chemistry of Transient P‐Chlorophosphanyl Complexes

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Özbolat‐Schön, A., Bode, M., Schnakenburg, G., Anoop, A., van Gastel, M., Neese, F., et al. (2010). Insights into the Chemistry of Transient P‐Chlorophosphanyl Complexes. Angewandte Chemie International Edition, 49(38), 6894-6898. doi:10.1002/anie.201002885.

Cite as: https://hdl.handle.net/21.11116/0000-0008-0FAB-8

Abstract

C-P or C=P? One‐electron oxidation of Li/Cl phosphinidenoid complexes led to the discovery of transient P‐chlorophosphanyl complexes 1. Subsequent cross‐coupling and rearrangement or elimination reactions yielded 2 and 3; the latter is the first structurally characterized phosphaquinomethane complex. ESR spectroscopy and DFT calculations support the existence of short‐lived P‐centered radicals.