Unsymmetrical one-electron oxidized Ni(II)–bis(salicylidene) complexes: a 
protonation-induced shift of the oxidation site

Kochem, Amélie; Orio, Maylis; Jarjayes, Olivier; Neese, Frank; Thomas, Fabrice

doi:10.1039/C0CC01775B

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Unsymmetrical one-electron oxidized Ni(II)–bis(salicylidene) complexes: a protonation-induced shift of the oxidation site

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Kochem, A., Orio, M., Jarjayes, O., Neese, F., & Thomas, F. (2010). Unsymmetrical one-electron oxidized Ni(II)–bis(salicylidene) complexes: a protonation-induced shift of the oxidation site. Chemical Communications, 46(36), 6765-6767. doi:10.1039/C0CC01775B.

Cite as: https://hdl.handle.net/21.11116/0000-0008-0F82-5

Abstract

The spin density in the nickel(II) radical salen complex (2˙)⁺ could be localized on a specific ring by controlling the acidity of the medium.