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EPR Spectroscopy of a Family of CrIII7MII (M = Cd, Zn, Mn, Ni) “Wheels”: Studies of Isostructural Compounds with Different Spin Ground States

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Piligkos,  Stergios
Department of Chemistry, University of Copenhagen;
Research Department Wieghardt, Max Planck Institute for Bioinorganic Chemistry, Max Planck Society;
School of Chemistry, The University of Manchester;

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Bill,  Eckhard
Research Department Wieghardt, Max Planck Institute for Bioinorganic Chemistry, Max Planck Society;

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Neese,  Frank
Research Department Wieghardt, Max Planck Institute for Bioinorganic Chemistry, Max Planck Society;

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Citation

Piligkos, S., Weihe, H., Bill, E., Neese, F., El Mkami, H., Smith, G. M., et al. (2009). EPR Spectroscopy of a Family of CrIII7MII (M = Cd, Zn, Mn, Ni) “Wheels”: Studies of Isostructural Compounds with Different Spin Ground States. Chemistry – A European Journal, 15(13), 3152-3167. doi:10.1002/chem.200801895.


Cite as: http://hdl.handle.net/21.11116/0000-0008-333B-D
Abstract
Spinning wheels: The presented highly resolved multifrequency continuous wave EPR spectra (e.g., see figure) of the heterooctametalic “wheels” Cr7M provide rare examples of high nuclearity polymetallic systems where detailed information on the spin‐Hamiltonian parameters of the ground and excited spin states is observed.