EPR Spectroscopy of a Family of CrIII7MII (M = Cd, Zn, Mn, Ni) “Wheels”: 
Studies of Isostructural Compounds with Different Spin Ground States

Piligkos, Stergios; Weihe, Høgni; Bill, Eckhard; Neese, Frank; El Mkami, Hassane; Smith, Graham M.; Collison, David; Rajaraman, Gopalan; Timco, Grigore A.; Winpenny, Richard E. P.; McInnes, Eric J. L.

doi:10.1002/chem.200801895

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EPR Spectroscopy of a Family of Cr^III₇M^II (M = Cd, Zn, Mn, Ni) “Wheels”: Studies of Isostructural Compounds with Different Spin Ground States

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Piligkos, Stergios
Department of Chemistry, University of Copenhagen;
Research Department Wieghardt, Max Planck Institute for Bioinorganic Chemistry, Max Planck Society;
School of Chemistry, The University of Manchester;

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Bill, Eckhard
Research Department Wieghardt, Max Planck Institute for Bioinorganic Chemistry, Max Planck Society;

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Neese, Frank
Research Department Wieghardt, Max Planck Institute for Bioinorganic Chemistry, Max Planck Society;

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Citation

Piligkos, S., Weihe, H., Bill, E., Neese, F., El Mkami, H., Smith, G. M., et al. (2009). EPR Spectroscopy of a Family of Cr^III₇M^II (M = Cd, Zn, Mn, Ni) “Wheels”: Studies of Isostructural Compounds with Different Spin Ground States. Chemistry – A European Journal, 15(13), 3152-3167. doi:10.1002/chem.200801895.

Cite as: http://hdl.handle.net/21.11116/0000-0008-333B-D

Abstract

Spinning wheels: The presented highly resolved multifrequency continuous wave EPR spectra (e.g., see figure) of the heterooctametalic “wheels” Cr₇M provide rare examples of high nuclearity polymetallic systems where detailed information on the spin‐Hamiltonian parameters of the ground and excited spin states is observed.