NMR study of the quasi-one dimensional organic metal 
(perylene)2(AsF6)0.75(PF6)0.35 × 0.85 CH2Cl2

Wieland, J.; Haeberlen, U.; Schweitzer, D.; Keller, H.J.

doi:10.1016/0379-6779(87)90386-9

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NMR study of the quasi-one dimensional organic metal (perylene)2(AsF6)0.75(PF6)0.35 × 0.85 CH2Cl2

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Wieland, J.
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

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Haeberlen, U.
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

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Schweitzer, D.
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

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https://www.sciencedirect.com/science/article/pii/0379677987903869/pdf?md5=1738566f9d759a424aff1b93749bb9d2&pid=1-s2.0-0379677987903869-main.pdf
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Citation

Wieland, J., Haeberlen, U., Schweitzer, D., & Keller, H. (1987). NMR study of the quasi-one dimensional organic metal (perylene)2(AsF6)0.75(PF6)0.35 × 0.85 CH2Cl2. Synthetic Metals, 19(1-3), 393-398. doi:10.1016/0379-6779(87)90386-9.

Cite as: https://hdl.handle.net/21.11116/0000-0008-769E-2

Abstract

Measurements of the temperature and frequency dependences of the proton spin lattice relaxation rate and of the proton and carbon Knight shifts in the title compound are presented. The results are interpreted in terms of a quasi-one dimensional microscopic conduction electron mobility and of the local unpaired spin densities at the carbon sites of the perylene donor molecules. An estimate is given for the mean residence time τβ of a conduction electron on a stack of perylene molecules, τβ ≈ 3.5 10−10 s.