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Journal Article

Novel Crown Ethers with a Trithiadiazapentalene–Trithiotriuret Redox System

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Deege,  Alfred
Research Department Maier, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Hinrichs,  Heike
Research Department Maier, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Graubaum, H., Tittelbach, F., Lutze, G., Gloe, K., Mackrodt, M., Krüger, T., et al. (1997). Novel Crown Ethers with a Trithiadiazapentalene–Trithiotriuret Redox System. Angewandte Chemie International Edition, 36(15), 1648-1650. doi:10.1002/anie.199716481.


Cite as: https://hdl.handle.net/21.11116/0000-0008-9125-A
Abstract
The differentiated recognition of Ag1 and Hg11 can be achieved with the pentaleno crown ethers 1 by variation of the cavity through the reversible trithia-diazapentalene–trithiotriuret redox system (1⇌2). These compounds were obtained in a one-pot reaction of trithiadiazapentalenes with diamino polyethers of different chain lengths. n = 1–3, R = CH3, CH2C6H5.