Preparative LC separation and isolation of enantiomerically pure olefins

Köhler, J.; Deege, A.; Schomburg, G.

doi:10.1007/BF02258766

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Preparative LC separation and isolation of enantiomerically pure olefins

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Köhler, J.
Service Department Schomburg (GC), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Deege, A.
Service Department Schomburg (GC), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Schomburg, G.
Service Department Schomburg (GC), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Köhler, J., Deege, A., & Schomburg, G. (1984). Preparative LC separation and isolation of enantiomerically pure olefins. Chromatographia, 18, 119-124. doi:10.1007/BF02258766.

Cite as: https://hdl.handle.net/21.11116/0000-0008-9B81-7

Abstract

Diastereomer formation by the reaction of chiral olefins with optically active platinum complexes followed by LC separation of the diastereomers, and on-line or off-line release of the olefins from the complexes by ligand exchange yield optically pure enantiomers.

The 100% dextrostetatory enantiomer of exo-2-vinylbicyclo[2.2.1]heptane (vinylnorbornane) could be isolated by an off-line method and was used for polarimetric measurements before and after preparative scale gas chromatographic clean-up.

The initial valuable platinum complex could be easily recovered without loss.