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Journal Article

Iron-mediated C–H coupling of arenes and unactivated terminal alkenes directed by sulfur

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Citation

Cavanagh, C. W., Aukland, M. H., Hennessy, A., & Procter, D. J. (2015). Iron-mediated C–H coupling of arenes and unactivated terminal alkenes directed by sulfur. Chemical Communications, 51(45), 9272-9275. doi:10.1039/C5CC02676H.


Cite as: https://hdl.handle.net/21.11116/0000-0008-9B8E-A
Abstract
A sulfur-directed Fe(III)-mediated ortho C–H coupling of arenes with unactivated terminal alkenes gives products of regioselective alkene chloroarylation. The novel mechanism involves redox-activation of the arene partner and alkene addition to the resultant aryl radical cation.