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Journal Article

Amino−Organolithium Compounds and their Aggregation for the Synthesis of Amino−Organoaluminium Compounds

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Bodach,  Alexander
Research Group Felderhoff, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Ortmeyer,  Jochen
Research Group Felderhoff, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Institute of Inorganic Chemistry, RWTH Aachen University;

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Herrmann,  Bastian
Research Group Felderhoff, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Felderhoff,  Michael
Research Group Felderhoff, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Bodach, A., Ortmeyer, J., Herrmann, B., & Felderhoff, M. (2021). Amino−Organolithium Compounds and their Aggregation for the Synthesis of Amino−Organoaluminium Compounds. European Journal of Inorganic Chemistry, 2021(23), 2248-2256. doi:10.1002/ejic.202100224.


Cite as: https://hdl.handle.net/21.11116/0000-0008-C377-6
Abstract
A structural study of amino−organolithium compounds is presented with an emphasis on their aggregation as tetramers and dimers. These compounds were further used to generate their corresponding aluminium compounds whose crystal structures as well as those of neophyllithium and decomposition products are reported too. This study provides additional data for the future design and synthesis of amino−organolithium and -aluminium compounds.