English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse
  1. View item / 
  2. Item Summary

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

The Reactivity of the Imine Bond within Polynuclear Nickel(II) Complexes

MPS-Authors
/persons/resource/persons216826

Pantazis,  Dimitrios A.
Research Group Pantazis, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Siedzielnik, M., Pantazis, D. A., Bruniecki, J., Kaniewska-Laskowska, K., & Dołęga, A. (2021). The Reactivity of the Imine Bond within Polynuclear Nickel(II) Complexes. Crystals, 11(5): 512. doi:10.3390/cryst11050512.


Cite as: https://hdl.handle.net/21.11116/0000-0008-C37A-3
Abstract
Three novel Ni complexes with the Schiff base ligand 2-methoxy-6-(E-2-pyridyliminomethyl)-phenol (L1) are described. In comparison with the similar 2-(pyridine-2-ylimino-methyl)phenol (pymp), the mode of coordination of L1 is altered due to the presence of methoxy substituent introducing the sterical hindrance. During the synthesis of the complexes, partial hydrolysis of the ligand was observed. Since such immediate hydrolysis of L1 was not detected during the reactions of Zn(II) and Cu(II) salts with L1, the DFT calculated structures of a series of similar Zn, Cu, Ni, and Co complexes with L1 are compared to account for the phenomenon.