Transport coefficients of an ion exchange membrane and their concentration 
dependence

Wiedner, Günther; Woermann, Dietrich

doi:10.1002/bbpc.19750791008

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Transport coefficients of an ion exchange membrane and their concentration dependence

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Wiedner, Günther
Department of Physical Chemistry, Max Planck Institute of Biophysics, Max Planck Society;

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Woermann, Dietrich
Department of Physical Chemistry, Max Planck Institute of Biophysics, Max Planck Society;
lnstitut für Physikalische Chemie, Universität Köln, Germany;

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Citation

Wiedner, G., & Woermann, D. (1975). Transport coefficients of an ion exchange membrane and their concentration dependence. Berichte der Bunsen-Gesellschaft, 79(10), 868-878. doi:10.1002/bbpc.19750791008.

Cite as: https://hdl.handle.net/21.11116/0000-0008-C7E4-6

Abstract

For a system consisting of a cation exchange membrane, potassium chloride and water, the complete matrix of the phenomenological transport coefficients appearing in the linear laws of the thermodynamics of irreversible processes is determined under isothermal conditions. The experiments are carried out at different mean salt concentrations to study the concentration dependence of the transport coefficients. The symmetry relations of Onsager are used to check the consistency of the experimental results. The results are discussed in terms of the model of the membrane with narrow pores.