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Coverage dependence of the O-Ru stretch mode on Ru(0001)

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Jacobi,  Karl
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

He, P.-M., & Jacobi, K. (1999). Coverage dependence of the O-Ru stretch mode on Ru(0001). Acta Physica Sinica, 48(2), 284-288. doi:10.7498/aps.48.284.


Cite as: https://hdl.handle.net/21.11116/0000-0008-DCDA-B
Abstract
Oxygen overlayers with different coverages on Ru(0001) were prepared by dissociative adsorption of O2, and sequential dissociation of O2 and NO2. The high-resolution electron energy loss spectroscopy measurements showed a strong coverage dependence of O-Ru strectch mode. The vibrational energy of this mode shifts from 54 meV for the lower coverage limit (θO→0.0) upward to 81 meV for densely packed (1×1)-O overlayer (θO=1.0).