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Fullerene-based ruthenium catalysts: a novel approach for anchoring metal to carbonaceous supports. II. Hydrogenation activity

MPS-Authors
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Braun,  Thomas
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Wohlers,  Michael
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Belz,  Thilo
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Braun, T., Wohlers, M., Belz, T., & Schlögl, R. (1997). Fullerene-based ruthenium catalysts: a novel approach for anchoring metal to carbonaceous supports. II. Hydrogenation activity. Catalysis Letters, 43, 175-180. doi:10.1023/A:1018950925046.


Cite as: https://hdl.handle.net/21.11116/0000-0008-E071-B
Abstract
The influence of fullerenes and related support materials on the catalytic properties of ruthenium was investigated. The catalytic
behaviour of catalysts based on C60, raw fullerene black, extracted fullerene black, cathode deposit, and graphite was examined using low-temperature CO hydrogenation and liquid-phase hydrogenation of 2-cyclohexenone at atmospheric pressure. The relevance
of non-six-membered carbon rings (NSMCR) in support materials on the stability and catalytic performance of the Ru particles will be illustrated.