Fullerene-based ruthenium catalysts: a novel approach for anchoring metal to 
carbonaceous supports. II. Hydrogenation activity

Braun, Thomas; Wohlers, Michael; Belz, Thilo; Schlögl, Robert

doi:10.1023/A:1018950925046

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Fullerene-based ruthenium catalysts: a novel approach for anchoring metal to carbonaceous supports. II. Hydrogenation activity

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Braun, Thomas
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Wohlers, Michael
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Belz, Thilo
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Schlögl, Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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引用

Braun, T., Wohlers, M., Belz, T., & Schlögl, R. (1997). Fullerene-based ruthenium catalysts: a novel approach for anchoring metal to carbonaceous supports. II. Hydrogenation activity. Catalysis Letters, 43, 175-180. doi:10.1023/A:1018950925046.

引用: https://hdl.handle.net/21.11116/0000-0008-E071-B

要旨

The influence of fullerenes and related support materials on the catalytic properties of ruthenium was investigated. The catalytic
behaviour of catalysts based on C₆₀, raw fullerene black, extracted fullerene black, cathode deposit, and graphite was examined using low-temperature CO hydrogenation and liquid-phase hydrogenation of 2-cyclohexenone at atmospheric pressure. The relevance
of non-six-membered carbon rings (NSMCR) in support materials on the stability and catalytic performance of the Ru particles will be illustrated.