Non-stationary reaction rates in a radiation-induced chemical reaction by means 
of conductivity measurements

Lotz, Ansbert Peter; Schmidt, Klaus

doi:10.1038/201493a0

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Non-stationary reaction rates in a radiation-induced chemical reaction by means of conductivity measurements

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Lotz, Ansbert Peter
Max Planck Institute of Biophysics, Max Planck Society;

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引用

Lotz, A. P., & Schmidt, K. (1964). Non-stationary reaction rates in a radiation-induced chemical reaction by means of conductivity measurements. Nature, 201(4918), 493-495. doi:10.1038/201493a0.

引用: https://hdl.handle.net/21.11116/0000-0008-F30A-B

要旨

RATE constants of radiation-induced chemical reactions, or lifetimes of intermediates, can be measured by the rotating sector method. This is usually done by evaluating the final product yield as a function of pulse frequency. Thus, Freeman, Van Cleave and Spinks examined the formation of hydrochloric acid in aqueous solutions of chloral hydrate under ionizing irradiation. They found a mean chain lifetime of about 0.1 sec.