Photochemistry of Methane on Pd/Al2O3 Model Catalysts: Control of 
Photochemistry on Transition Metal Surfaces

Watanabe, Kazuo; Matsumoto, Yoshiyasu; Kampling, Margarethe; Al-Shamery, Katharina; Freund, Hans-Joachim

doi:10.1002/(SICI)1521-3773(19990802)38:15<2192::AID-ANIE2192>3.0.CO;2-X

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Photochemistry of Methane on Pd/Al₂O₃ Model Catalysts: Control of Photochemistry on Transition Metal Surfaces

MPS-Authors

/persons/resource/persons21694

Kampling, Margarethe
Chemical Physics, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons248304

Al-Shamery, Katharina
Chemical Physics, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21524

Freund, Hans-Joachim
Chemical Physics, Fritz Haber Institute, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Watanabe, K., Matsumoto, Y., Kampling, M., Al-Shamery, K., & Freund, H.-J. (1999). Photochemistry of Methane on Pd/Al₂O₃ Model Catalysts: Control of Photochemistry on Transition Metal Surfaces. Angewandte Chemie International Edition, 38(15), 2192-2194. doi:10.1002/(SICI)1521-3773(19990802)38:15<2192:AID-ANIE2192>3.0.CO;2-X.

Cite as: https://hdl.handle.net/21.11116/0000-0009-061D-1

Abstract

The mean size of the Pd clusters deposited on an Al₂O₃ thin film influences the efficiency of photodissociation of CD₄ into CD₃ and D as well as the photodesorpion upon irradiation with 193-nm laser light. The picture shows the degree of desorption on Pd clusters of various sizes (as well as on a Pd(111) single-crystal surface) as a function of temperature; the values given refer to the average thickness of the evaporated metal layer.