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Bell–like [Ga5] clusters in Sr3Li5Ga5: synthesis, crystal structure and bonding analysis.

MPS-Authors
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Kotsch,  Matthias
Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Prots,  Yurii
Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Ormeci,  Alim
Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Kohout,  Miroslav
Miroslav Kohout, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Grin,  Yuri
Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Kotsch, M., Prots, Y., Ormeci, A., Senyshyn, A., Kohout, M., & Grin, Y. (2021). Bell–like [Ga5] clusters in Sr3Li5Ga5: synthesis, crystal structure and bonding analysis. Zeitschrift für anorganische und allgemeine Chemie, 647, 1797-1803. doi:10.1002/zaac.202100147.


Cite as: https://hdl.handle.net/21.11116/0000-0009-1D3A-7
Abstract
During the search for a possible replacement of the europium in the structure Eu3Li5+xGa5−x (x = 0.15) in order to facilitate the analysis of the chemical bonding in the bell–like [Ga5] clusters, the isostructural compound Sr3Li5Ga5 (space group R (Formula presented.) m, a = 9.6040(5) Å, c = 22.061(1) Å) was discovered. A detailed investigation of the bonding situation in the first five–membered nonconvex Ga cluster utilizing the electron localizability approach became possible, revealing not only first signs of a transition from a Zintl to a Wade cluster, but also the presence of a [Sr6] polycation. © 2021 The Authors. Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH