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Journal Article

Photoelectron diffraction determination of the local adsorption geometry of CO on Cu(210)

MPS-Authors
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Terborg,  Ralf
Fritz Haber Institute, Max Planck Society;

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Polcik,  Martin
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Baumgärtel,  Peter
Fritz Haber Institute, Max Planck Society;

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Hoeft,  Jon Tobias
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Bradshaw,  Alexander M.
Fritz Haber Institute, Max Planck Society;

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Woodruff,  David Phillip
Fritz Haber Institute, Max Planck Society;
Department of Physics, University of Warwick;

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Citation

Terborg, R., Polcik, M., Toomes, R. L., Baumgärtel, P., Hoeft, J. T., Bradshaw, A. M., et al. (2001). Photoelectron diffraction determination of the local adsorption geometry of CO on Cu(210). Surface Science, 473(3), 203-212. doi:10.1016/S0039-6028(00)00971-7.


Cite as: https://hdl.handle.net/21.11116/0000-0009-3E58-0
Abstract
Using C 1s and O 1s scanned-energy mode photoelectron diffraction, the local adsorption site and orientation of CO adsorbed on Cu(210) has been determined. The results show that the molecule adsorbs in an essential on-top site through the C atom with C–Cu and C–O bondlengths generally consistent with previous studies on low index Cu surfaces. The molecule has a significant tilt (18±6°) of the C–O axis away from the surface normal, with components both perpendicular and parallel to the [001] steps on this surface.