English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse
  1. View item / 
  2. Item Summary

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Local adsorption geometry of 2-methyl-pyridine on Cu(110) determined by photoelectron diffraction

MPS-Authors
/persons/resource/persons22162

Terborg,  Ralf
Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21969

Polcik,  Martin
Chemical Physics, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21633

Hoeft,  Jon Tobias
Chemical Physics, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21727

Kittel,  Martin
Chemical Physics, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21399

Bradshaw,  Alexander M.
Fritz Haber Institute, Max Planck Society;

Woodruff,  D. P.
Fritz Haber Institute, Max Planck Society;
Physics Department, University of Warwick;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Terborg, R., Polcik, M., Hoeft, J. T., Kittel, M., Pascal, M., Kang, J. H., et al. (2000). Local adsorption geometry of 2-methyl-pyridine on Cu(110) determined by photoelectron diffraction. Surface Science, 457(1-2), 1-10. doi:10.1016/S0039-6028(00)00372-1.


Cite as: https://hdl.handle.net/21.11116/0000-0009-2EFB-A
Abstract
Using N 1s scanned-energy mode photoelectron diffraction, together with N K-edge near-edge absorption fine structure, the local adsorption site and molecular orientation of 2-methyl-pyridine adsorbed on Cu(110) has been
determined and the results are compared with a similar study of pyridine adsorption on the same surface. The molecule is found to bond to the surface through the N atom that occupies a near-atop site. The molecular plane is almost perpendicular to the surface but twisted into an azimuth away from the two principal high-symmetry directions of the surface. The aromatic ring is also tilted within the molecular plane such as to increase the separation of the
methyl group away from the surface.