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Effects of Mo on the mechanical behavior of γ/γʹ-strengthened Co–Ti-based alloys

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Lee,  Subin
Advanced Transmission Electron Microscopy, Structure and Nano-/ Micromechanics of Materials, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society;

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Makineni,  Surendra Kumar
Atom Probe Tomography, Microstructure Physics and Alloy Design, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society;

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Raabe,  Dierk
Microstructure Physics and Alloy Design, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society;

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Citation

Im, H. J., Lee, S., Choi, W. S., Makineni, S. K., Raabe, D., Ko, W.-S., et al. (2020). Effects of Mo on the mechanical behavior of γ/γʹ-strengthened Co–Ti-based alloys. Acta Materialia, 197, 69-80. doi:10.1016/j.actamat.2020.07.037.


Cite as: https://hdl.handle.net/21.11116/0000-0009-6E56-C
Abstract
We investigated the flow behavior of γ/γʹ-strengthened Co-12Ti and Co-12Ti-4Mo (at.) alloys at room and elevated temperatures (up to 900°C) by electron microscopy and density functional theory. The Mo-added alloy exhibited an enhanced compressive yield strength and strain hardening behavior as compared to the reference binary alloy. This behavior could be attributed to a ~25 larger γʹ volume fraction and ~7 higher planar fault energies in Co-12Ti-4Mo. Using electron channeling contrast imaging, we observed interrupted slip bands in the Co-12Ti-4Mo alloy deformed to a strain of 6, which led to enhanced strain hardening, in contrast to extended slip bands along 111 planes in the Co-12Ti alloy. Interrupted slip band formation in Co-12Ti-4Mo could be explained by rapid exhaustion of dislocation sources and a higher energy barrier required to cut the γʹ precipitates. These effects are due to a reduced γ channel width and substantial hardening effect of γʹ-Co3(Ti,Mo) in the ternary alloy as well as due to the large shear modulus difference between γʹ and γ. © 2020