A Chiral Sulfoxide-Based C–H Acid

Höfler, Denis; Kaupmees, Karl; Leito, Ivo; List, Benjamin

doi:10.1055/a-1695-4516

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A Chiral Sulfoxide-Based C–H Acid

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Höfler, Denis
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List, Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Höfler, D., Kaupmees, K., Leito, I., & List, B. (2022). A Chiral Sulfoxide-Based C–H Acid. Synlett, 33(1), 45-47. doi:10.1055/a-1695-4516.

Cite as: https://hdl.handle.net/21.11116/0000-0009-89CC-7

Abstract

We report the design and synthesis of a strong, chiral, enantiopure sulfoxide-based C–H acid. Single crystal X-ray analysis confirms the proposed structure and its absolute configuration. The new motif shows a high acidity and activity in Brønsted and Lewis acid catalyzed transformations. So far,only little to no enantioselectivities were achieved.