English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse
  1. View item / 
  2. Item Summary

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Thermal Decomposition of Silver Oxide Monitored by Raman Spectroscopy: From AgO Units to Oxygen Atoms Chemisorbed on the Silver Surface

MPS-Authors
/persons/resource/persons21954

Pettinger,  Bruno
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21329

Bao,  Xinhe
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

Wilcock,  Ian
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21898

Muhler,  Martin
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22071

Schlögl,  Robert
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21498

Ertl,  Gerhard
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Pettinger, B., Bao, X., Wilcock, I., Muhler, M., Schlögl, R., & Ertl, G. (1994). Thermal Decomposition of Silver Oxide Monitored by Raman Spectroscopy: From AgO Units to Oxygen Atoms Chemisorbed on the Silver Surface. Angewandte Chemie, International Edition in English, 33(1), 85-86. doi:10.1002/anie.199400851.


Cite as: https://hdl.handle.net/21.11116/0000-0009-8D4F-1
Abstract
When Ag7O8NO3 is heated in an O2-free atmosphere between 300 and 930 K, its AgO units (300–480 K) are transformed into Ag2O units (480–580 K) and ultimately into metallic Ag. A strongly chemisorbed Oγ species is found on the Ag surface at temperatures between 580 and 900 K which participates in the catalytic oxidation of methanol to give formaldehyde. The various O species were characterized by Raman spectroscopy.