Synthesis and Characterisation of Transition Metal Fullerides

Werner, Harald; Wohlers, Michael; Belz, Thilo; Schlögl, Robert

doi:10.1080/10587259408051704

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Synthesis and Characterisation of Transition Metal Fullerides

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Werner, H., Wohlers, M., Belz, T., & Schlögl, R. (1994). Synthesis and Characterisation of Transition Metal Fullerides. Molecular Crystals and Liquid Crystals Science and Technology Section A-Molecular Crystals and Liquid Crystals, 245(1), 295-300. doi:10.1080/10587259408051704.

Cite as: https://hdl.handle.net/21.11116/0000-0009-8E47-8

Abstract

Complexes of group VIII metals in low oxidation numbers react in solution with fullerene to yield structurally ill-defined compounds with reproducible compositions and properties. A variety of characterisation methods (analysis, XRD, FT-IR, TPD) indicate that the transition metals are located in the interstices of the fullerene lattice being distorted by the volume of the olgonuclear complexes with partly coordinated residual ligands. The fullerene molecules complete the coordination shells of these catalytically active materials.