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The adsorption and dehydrogenation of cyclohexane on the (1 × 1) and (5 × 20) surfaces of Pt{100}

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Lamont,  Christine L. A.
University of Huddersfield;
Fritz Haber Institute, Max Planck Society;

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Borbach,  Markus
Fritz Haber Institute, Max Planck Society;

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Stenzel,  W.
Fritz Haber Institute, Max Planck Society;

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Conrad,  Horst
Fritz Haber Institute, Max Planck Society;

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Bradshaw,  Alexander M.
Fritz Haber Institute, Max Planck Society;

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Citation

Lamont, C. L. A., Borbach, M., Stenzel, W., Conrad, H., & Bradshaw, A. M. (1994). The adsorption and dehydrogenation of cyclohexane on the (1 × 1) and (5 × 20) surfaces of Pt{100}. Chemical Physics Letters, 230(3), 265-270. doi:10.1016/0009-2614(94)01158-3.


Cite as: https://hdl.handle.net/21.11116/0000-0009-99CF-2
Abstract
The adsorption and dehydrogenation of cyclohexane on the (1 × 1) and (5 × 20) surfaces of Pt{100} have been investigated using EELS. On both surfaces dehydrogenation of cyclohexane to benzene occurs. The reactivity of the (5 × 20) surface, however, is three to four orders of magnitude lower than that of both the (1 × 1) surface and the topographically similar Pt{111} surface. The high reactivity of the (1 × 1) surface is surprising since no softened C-H mode is observed.