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Sticking coefficient for dissociative adsorption of N2 on Ru single‐crystal surfaces

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Dietrich,  Holger
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Geng,  Peter
Fritz Haber Institute, Max Planck Society;

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Jacobi,  Karl
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Ertl,  Gerhard
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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1.470836.pdf
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Citation

Dietrich, H., Geng, P., Jacobi, K., & Ertl, G. (1996). Sticking coefficient for dissociative adsorption of N2 on Ru single‐crystal surfaces. The Journal of Chemical Physics, 104(1), 375-381. doi:10.1063/1.470836.


Cite as: https://hdl.handle.net/21.11116/0000-0009-ACEC-C
Abstract
The dissociative chemisorption of N2 on Ru(0001), Ru(101̄0), and Ru(112̄1) surfaces at 300 K was studied by means of high‐resolution electron energy loss spectroscopy and thermal desorption spectroscopy. The initial sticking coefficient was determined to s0=(1±0.8)×10−12, within the limits of error independent of surface orientation. On Ru(101̄0) and Ru(112̄1) small amounts of N can be dissolved into the subsurface region.