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A HREELS investigation of benzenePT(111): the b2g(π∗) resonance

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Dippel,  Olaf
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Cemic,  F.
Fritz Haber Institute, Max Planck Society;

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Hasselbrink,  Eckart
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Dippel, O., Cemic, F., & Hasselbrink, E. (1996). A HREELS investigation of benzenePT(111): the b2g(π∗) resonance. Surface Science, 357-358, 190-194. doi:10.1016/0039-6028(96)00087-8.


Cite as: https://hdl.handle.net/21.11116/0000-0009-AD21-F
Abstract
For benzene chemisorbed on Pt(111) a negative ion resonance has been found at 2.1 eV above the vacuum energy. The resonance is assigned to the b2g(π∗) orbital of benzene. The shift of its energy upon adsorption is discussed in the light of the chemical bonding of the molecule to the surface.