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Emergent physical properties of perovskite-type oxides prepared under high pressure

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Wang,  Xiao
Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Ye, X., Wang, X., Liu, Z., Zhou, B., Zhou, L., Deng, H., et al. (2021). Emergent physical properties of perovskite-type oxides prepared under high pressure. Dalton Transactions, 1-9. doi:10.1039/d1dt03551g.


Cite as: http://hdl.handle.net/21.11116/0000-0009-C332-2
Abstract
The perovskite ABO(3) family demonstrates a wide variety of structural evolutions and physical properties and is arguably the most important family of complex oxides. Chemical substitutions of the A- and/or B-site and modulation of oxygen content can effectively regulate their electronic behaviors and multi-functional performances. In general, the BO6 octahedron represents the main unit controlling the electronic and magnetic properties while the A-site ion is often not involved. However, a series of unconventional perovskite materials have been recently synthesized under high pressure, such as the s-d level controlled Pb-based perovskite family and quadruple perovskite oxides containing transition metal ions at the A-site. In these compounds, the intersite A-B correlations play an important role in electronic behaviors and further induce many emergent physical properties.