Electron Spin Resonance Spectroscopic Investigation of the Rotational Motion of 
Self-Assembled Fatty Acid Films on Al2O3/NiAl(110)

Risse, T.; Hill, T.; Beckendorf, M.; Katter, U. J.; Schlienz, H.; Hamann, H.; Freund, Hans-Joachim

doi:10.1021/la9606759

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Electron Spin Resonance Spectroscopic Investigation of the Rotational Motion of Self-Assembled Fatty Acid Films on Al₂O₃/NiAl(110)

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Citation

Risse, T., Hill, T., Beckendorf, M., Katter, U. J., Schlienz, H., Hamann, H., et al. (1996). Electron Spin Resonance Spectroscopic Investigation of the Rotational Motion of Self-Assembled Fatty Acid Films on Al₂O₃/NiAl(110). Langmuir, 12(23), 5512-5514. doi:10.1021/la9606759.

Cite as: https://hdl.handle.net/21.11116/0000-0009-BFDA-B

Abstract

We report on the first electron spin resonance (ESR) investigation of the molecular rotational motion of self-assembled monolayers. We present results on fatty acid films grown on a thin Al₂₃ film. The spectra reveal a distinct temperature and coverage dependence. The changes in the line shape with variation of the spin labels location along the alkyl chain allow insight into the internal dynamics of self-assembled films.