English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Bismuth-rich bimetallic clusters (CuBi8)3+ and [MBi10]4+ (M = Pd, Pt) from ionothermal synthesis

MPS-Authors
/persons/resource/persons126823

Ruck,  Michael
Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Knies, M., & Ruck, M. (2021). Bismuth-rich bimetallic clusters (CuBi8)3+ and [MBi10]4+ (M = Pd, Pt) from ionothermal synthesis. Zeitschrift für Naturforschung, B: A Journal of Chemical Sciences, 1-5. doi:10.1515/znb-2021-0159.


Cite as: https://hdl.handle.net/21.11116/0000-0009-F54B-F
Abstract
The reaction of Bi, BiBr3, and CuBr in the Lewis-acidic ionic liquid [BMIm]Br·4AlBr3 (BMIm = 1-n-butyl-3-limidazolium) at 180 °C yielded air-sensitive, shiny black crystals of (CuBi8)[AlBr4]2[Al2Br7]. Crystals of [MBi10][AlCl4]4 (M = Pd, Pt) were obtained by reacting Bi, BiCl3, and MCl2 under similar conditions. The structures have been determined by X-ray diffraction on single-crystals and were found to be very similar to that of the known analogues with other halogens, although not isostructural. In crystals of the complex salts, polyhedral bimetallic clusters (CuBi8)3+ or [MBi10]4+ are embedded in matrices of halogenidoaluminate anions. The heteroatomic nido-cluster (CuBi8)3+ consists of a (Bi8)2+ square antiprism η4-coordinating a copper(I) cation. In the cluster cation [MBi10]4+, the metal atoms M center a pentagonal antiprism of bismuth atoms. © 2021 Walter de Gruyter GmbH, Berlin/Boston 2021.