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Henry's law constants (IUPAC Recommendations 2021)

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Sander,  Rolf
Atmospheric Chemistry, Max Planck Institute for Chemistry, Max Planck Society;

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Citation

Sander, R., Acree Jr., W. E., De Visscher, A., Schwartz, S. E., & Wallington, T. J. (2022). Henry's law constants (IUPAC Recommendations 2021). Pure and Applied Chemistry, 94(1), 71-85. doi:10.1515/pac-2020-0302.


Cite as: https://hdl.handle.net/21.11116/0000-0009-CBB6-5
Abstract
Henry’s law states that the abundance of a volatile solute dissolved in a liquid is proportional to its abundance in the gas phase. It applies at equilibrium and in the limit of infinite dilution of the solute. For historical reasons, numerous different definitions, names, and symbols are used in the literature to express the proportionality coefficient, denoted the “Henry’s law constant”. Here, a consistent set of recommendations is presented. An important distinction is made between two new recommended reciprocal quantities: “Henry’s law solubility constant” (H s) and “Henry’s law volatility constant” (H v). Eight recommended variants of H s and H v are described and relations among them presented.