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Journal Article

New interpretation of Penning spectra from alkali-metal atoms chemisorbed on metal surfaces

MPS-Authors
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Hemmen,  Ralf
Fritz Haber Institute, Max Planck Society;

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Conrad,  Horst
Fritz Haber Institute, Max Planck Society;

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PhysRevLett.67.1314.pdf
(Publisher version), 200KB

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Citation

Hemmen, R., & Conrad, H. (1991). New interpretation of Penning spectra from alkali-metal atoms chemisorbed on metal surfaces. Physical Review Letters, 67(10), 1314-1317. doi:10.1103/PhysRevLett.67.1314.


Cite as: https://hdl.handle.net/21.11116/0000-0009-F5CE-B
Abstract
Penning deexcitation spectra of alkali atoms adsorbed on metals show an intense peak at the Fermi level for coverages around the work-function minimum. This strong electron emission is assigned to the decay of a core-excited negative He-ion created by resonance transition of a substrate electron into the affinity level of the metastable rare-gas atom. The formation of this species also easily provides an explanation for the observed He* singlet-triplet conversion.