Xenofuranones A and B: Phenylpyruvate dimers from Xenorhabdus szentirmaii

Brachmann, Alexander O.; Forst, Steven; Furgani, Ghazala M.; Fodor, Andras; Bode, Helge B.

doi:10.1021/np060409n

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Xenofuranones A and B: Phenylpyruvate dimers from Xenorhabdus szentirmaii

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Brachmann, A. O., Forst, S., Furgani, G. M., Fodor, A., & Bode, H. B. (2006). Xenofuranones A and B: Phenylpyruvate dimers from Xenorhabdus szentirmaii. JOURNAL OF NATURAL PRODUCTS, 69(12), 1830-1832. doi:10.1021/np060409n.

Cite as: https://hdl.handle.net/21.11116/0000-000A-0570-2

Abstract

Xenofuranones A (1) and B (2) have been isolated from cultures of the insect-pathogenic bacterium Xenorhabdus szentirmaii, and their structures were elucidated by NMR and mass spectroscopy. Both compounds show similarities to fungal furanones, and their biosynthesis was studied using a reversed approach by feeding putative C-12 precursors to an overall C-13 background in small-scale experiments followed by gas chromatographic analysis coupled to mass spectrometry.