Formation and Cleavage of a Sb−Sb Double Bond: From Carbene-Coordinated 
Distibenes to Stibinidenes

Krüger, Julia; Wölper, Christoph; Auer, Alexander A.; Schulz, Stephan

doi:10.1002/ejic.202100960

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Formation and Cleavage of a Sb−Sb Double Bond: From Carbene-Coordinated Distibenes to Stibinidenes

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Auer, Alexander A.
Research Group Auer, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Krüger, J., Wölper, C., Auer, A. A., & Schulz, S. (2022). Formation and Cleavage of a Sb−Sb Double Bond: From Carbene-Coordinated Distibenes to Stibinidenes. European Journal of Inorganic Chemistry, 2022(3): e202100960. doi:10.1002/ejic.202100960.

Cite as: https://hdl.handle.net/21.11116/0000-000A-2C3E-1

Abstract

Stibine [L(Cl)Ga]₂SbCl reacts with N-heterocyclic carbenes ^RNHC^Me to either ^RNHC^Me-coordinated distibenes L(Cl)Ga]SbSb(^RNHC^Me)Ga(Cl)L ((^RNHC^Me=Me, Et, i-Pr) or stibinidenes L(Cl)GaSb-^RNHC^Me (^RNHC^Me=Me, Et) after Sb−Sb bond cleavage. Energies of the products and possible reaction intermediates were calculated by DFT methods.