Structure elucidation of the core octasaccharide from Citrobacter PCM 1487 with 
the aid of 500-MHz, two-dimensional phase-sensitive correlated, 
relayed-coherence transfer, double-quantum, triple-quantum filtered, and N.O.E. 
1H-n.m.r. spectra

Dabrowski, Janusz; Hauck, Michael; Romanowska, Elzbieta; Gamian, Andrzej

doi:10.1016/0008-6215(88)80074-0

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Structure elucidation of the core octasaccharide from Citrobacter PCM 1487 with the aid of 500-MHz, two-dimensional phase-sensitive correlated, relayed-coherence transfer, double-quantum, triple-quantum filtered, and N.O.E. 1H-n.m.r. spectra

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Dabrowski, Janusz
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Hauck, Michael
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Zitation

Dabrowski, J., Hauck, M., Romanowska, E., & Gamian, A. (1988). Structure elucidation of the core octasaccharide from Citrobacter PCM 1487 with the aid of 500-MHz, two-dimensional phase-sensitive correlated, relayed-coherence transfer, double-quantum, triple-quantum filtered, and N.O.E. 1H-n.m.r. spectra. Carbohydrate Research, 180(2), 163-174. doi:10.1016/0008-6215(88)80074-0.

Zitierlink: https://hdl.handle.net/21.11116/0000-000A-54E9-1

Zusammenfassung

The main features of the primary structure of the octasaccharide, α-d-Glcp-(1→2)-α-d-Glcp-(1→2)-[α-d-GalpNAc- (1→3)]-α-d-Galp-(1→3)-α-d-Glcp-(1→3)-[α-ld-Hepp-(1→7)]-α-ld-Hepp-(1→3)-α-ld-Hep, have been determined in the ab initio manner by 1H-n.m.r. spectroscopy without resorting to biochemical methods of analysis. Several nontypical interresidue n.O.e. values point to a preferred solution conformation of the molecule.