Application of 1H/13C inversely correlated NMR spectroscopy to the 
determination of the stereochemistry of a polysubstituted [2.2]paracyclophane

Fischer, Rüdiger E.; Dabrowski, Janusz; Ejchart, Andrzej; Staab, Heinz A.

doi:10.1002/mrc.1260261006

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

タグ情報を表示リリース履歴を表示詳細要約

公開

学術論文

Application of 1H/13C inversely correlated NMR spectroscopy to the determination of the stereochemistry of a polysubstituted [2.2]paracyclophane

MPS-Authors

/persons/resource/persons219827

Fischer, Rüdiger E.
Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons92575

Dabrowski, Janusz
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons197270

Ejchart, Andrzej
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons95446

Staab, Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

External Resource

https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/10.1002/mrc.1260261006
(全文テキスト（全般）)

https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/epdf/10.1002/mrc.1260261006
(全文テキスト（全般）)

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

公開されているフルテキストはありません

付随資料 (公開)

There is no public supplementary material available

引用

Fischer, R. E., Dabrowski, J., Ejchart, A., & Staab, H. A. (1988). Application of 1H/13C inversely correlated NMR spectroscopy to the determination of the stereochemistry of a polysubstituted [2.2]paracyclophane. Magnetic Resonance in Chemistry, 26(10), 834-838. doi:10.1002/mrc.1260261006.

引用: https://hdl.handle.net/21.11116/0000-000A-5565-5

要旨

The relative orientation of substituents in the opposite rings of one of the isomeric 4,7-Dichloro-5,8,12,15-tetramethoxy-13,6-bis[4-(2-methoxycarbonylphenyl) butyl][2.2]paracyclophanes was determined by establishing by NOE their orientation relative to the bridge protons, which thus served as ‘space-spy nuclei’. The mutual orientation of these bridge protons was ascertained by the analysis of their coupling constants, obtained from a phasesensitive COSY spectrum. The 1H and 13C resonances were assigned with the aid of 1H COSY and 1H/13C inversely correlated spectra.