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Cross polarization in electron nuclear double resonance by satisfying the Hartmann-Hahn condition

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Brunner,  H.
Max Planck Institute for Medical Research, Max Planck Society;

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Hausser,  Karl H.
Max Planck Institute for Medical Research, Max Planck Society;

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引用

Brunner, H., Fritsch, R. H., & Hausser, K. H. (1989). Cross polarization in electron nuclear double resonance by satisfying the Hartmann-Hahn condition. Zeitschrift für Naturforschung, A: Physical Sciences, 42(12), 1456-1457. doi:10.1515/zna-1987-1217.


引用: https://hdl.handle.net/21.11116/0000-000A-5A35-6
要旨
The polarization of electronic spins S is transferred to nuclear spins / by cross relaxation in an electron nuclear double resonance experim ent. The cross relaxation becomes very efficient with a time constant Tcr o about 0.5 m icroseconds if the Hartmann-Hahn condition is satisfied for electronic spins S spin-locked to the microwave field B1,s in the rotating frame and for proton spins / in the static magnetic
field B0 .