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Abstract

The out-of-equilibrium dynamics of chemotactic active matter—be it animate or inanimate—is closely coupled to the environment, a chemical landscape shaped by secretions from the motile agents, fuel uptake, or autochemotactic signaling. This gives rise to complex collective effects, which can be exploited by the agents for colony migration strategies or pattern formation. We study such effects using an idealized experimental system: self-propelled microdroplets that communicate via chemorepulsive trails. We present a comprehensive experimental analysis that involves direct probing of the diffusing chemical trails and the trail–droplet interactions and use it to construct a generic theoretical model. We connect these repulsive autochemotactic interactions to the collective dynamics in emulsions, demonstrating a state of dynamical arrest: chemotactic self-caging.