Influence of the emission site on the photoelectron circular dichroism in 
trifluoromethyloxirane

Fehre, Kilian; Trinter, Florian; Novikovskiy, Nikolay M.; Grundmann, Sven; Tsitsonis, Dimitrios; Eckart, Sebastian; Bauer, Leonie; Hilzinger, Maria; Jahnke, Till; Dörner, Reinhard; Demekhin, Philipp V.; Schöffler, Markus S.

doi:10.1039/d2cp00143h

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

タグ情報を表示リリース履歴を表示詳細要約

公開

学術論文

Influence of the emission site on the photoelectron circular dichroism in trifluoromethyloxirane

MPS-Authors

/persons/resource/persons242626

Trinter, Florian
Institut für Kernphysik, Goethe-Universität Frankfurt;
Molecular Physics, Fritz Haber Institute, Max Planck Society;

External Resource

There are no locators available

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

d2cp00143h.pdf
(出版社版), 3MB

付随資料 (公開)

There is no public supplementary material available

引用

Fehre, K., Trinter, F., Novikovskiy, N. M., Grundmann, S., Tsitsonis, D., Eckart, S., Bauer, L., Hilzinger, M., Jahnke, T., Dörner, R., Demekhin, P. V., & Schöffler, M. S. (2022). Influence of the emission site on the photoelectron circular dichroism in trifluoromethyloxirane. Physical Chemistry Chemical Physics, 24(22), 13597-13604. doi:10.1039/d2cp00143h.

引用: https://hdl.handle.net/21.11116/0000-000A-AC0D-7

要旨

We report a joint experimental and theoretical study of the differential photoelectron circular dichroism (PECD) in inner-shell photoionization of uniaxially oriented trifluoromethyloxirane. By adjusting the photon energy of the circularly polarized synchrotron radiation, we address 1s-photoionization of the oxygen, different carbon, and all fluorine atoms. The photon energies were chosen such that in all cases electrons with a similar kinetic energy of about 11 eV are emitted. Employing coincident detection of electrons and fragment ions, we concentrate on identical molecular fragmentation channels for all of the electron-emitter scenarios. Thereby, we systematically examine the influence of the emission site of the photoelectron wave on the differential PECD. We observe large differences in the PECD signals. The present experimental results are supported by corresponding relaxed-core Hartree–Fock calculations.

This article is part of the themed collection: Festschrift Ivan Powis: Advances in Molecular Photoelectron Spectroscopy: Fundamentals & Application