Electron transfer in photoexcited porphyrin quinone cyclophanes

Mauzerall, David; Weiser, Jurgen; Staab, Heinz

doi:10.1016/S0040-4020(01)85153-X

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Electron transfer in photoexcited porphyrin quinone cyclophanes

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Weiser, Jurgen
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Staab, Heinz
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Mauzerall, D., Weiser, J., & Staab, H. (1989). Electron transfer in photoexcited porphyrin quinone cyclophanes. Tetrahedron, 45(15), 4807-4814. doi:10.1016/S0040-4020(01)85153-X.

Cite as: https://hdl.handle.net/21.11116/0000-000A-B551-E

Abstract

The striking difference in fractions of fast versus slow components ofelectron transfer of the porphyrin mono- and bis-quinone cyclophanes are attributed to an orbital symmetry effect between the porphyrin and the quinone.