Electron donor-acceptor [3.3]metacyclophanes: charge-transfer absorption of 
syn- and anti-isomers

Staab, Heinz A.; Döhling, Annelie; Krieger, Claus

doi:10.1016/S0040-4039(00)79684-5

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Electron donor-acceptor [3.3]metacyclophanes: charge-transfer absorption of syn- and anti-isomers

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Staab, Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Döhling, Annelie
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Krieger, Claus
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Staab, H. A., Döhling, A., & Krieger, C. (1991). Electron donor-acceptor [3.3]metacyclophanes: charge-transfer absorption of syn- and anti-isomers. Tetrahedron Letters, 32(20), 2215-2218. doi:10.1016/S0040-4039(00)79684-5.

Cite as: https://hdl.handle.net/21.11116/0000-000A-F0A1-0

Abstract

As electron donor-acceptor [3.3]metacyclophanes with dicyanoquinomethane as acceptor unit in different sterical arrangements the syn- anti isomers 3 and 4 were synthesized. Charge-transfer interactions are discussed with reference to the isomerization of 4 and 3 and to the absorption spectra.