A10Tl6O2 (A = K, Rb) cluster compounds combining structural features of 
thallium cluster anions and of alkali metal sub-oxides

Karpov, A.; Jansen, M.

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A₁₀Tl₆O₂ (A = K, Rb) cluster compounds combining structural features of thallium cluster anions and of alkali metal sub-oxides

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Karpov, A.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Jansen, M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Karpov, A., & Jansen, M. (2006). A₁₀Tl₆O₂ (A = K, Rb) cluster compounds combining structural features of thallium cluster anions and of alkali metal sub-oxides. Chemical Communications, 2006(16), 1706-1708.

Cite as: https://hdl.handle.net/21.11116/0000-000F-0315-6

Abstract

New alkali metal thallideoxides, A(10)Tl(6)O(2) (A = K, Rb),
crystallize in a unique structure consisting of hypoelectronic
[Tl-6](6-) clusters in the shape of compressed octahedra, together with
oxygen-centred alkali metal octahedra that have been identified as
constitutive of alkali metal sub-oxides.