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Journal Article

NMR studies of cation transport in the crystalline ion conductors MCF3SO3 (M = Li, Na) and Li7TaO6

MPS-Authors
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van Wüllen,  L.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Sofina,  N.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Hildebrandt,  L.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Mühle,  C.
Department Quantum Materials (Hidenori Takagi), Max Planck Institute for Solid State Research, Max Planck Society;
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Jansen,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

van Wüllen, L., Sofina, N., Hildebrandt, L., Mühle, C., & Jansen, M. (2006). NMR studies of cation transport in the crystalline ion conductors MCF3SO3 (M = Li, Na) and Li7TaO6. Solid State Ionics, 177(19-25), 1665-1672.


Cite as: https://hdl.handle.net/21.11116/0000-000E-FBA8-A
Abstract
In this contribution we present studies on the mechanism of ion
transport in crystalline solid electrolytes employing a range of
different solid state nuclear magnetic resonance (NMR) experiments. The
first part is devoted to the elucidation of a possible correlation of
cation transport and anion reorientation in the dynamically disordered
rotor phases of alkali trifluoromethane sulfonates MCF3SO3 (M = Li, Na)
employing Li-7, C-13, O-17 and Na-23 NMR line shape analysis, whereas
the second part focuses on the tracking of cation diffusion pathways in
the hexaoxometalate Li7TaO6 utilizing Li-6 1D and 2D exchange MAS NMR
approaches. (c) 2006 Elsevier B.V All rights reserved.