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Journal Article

Supramolecular intercluster compounds consisting of gold clusters and Keggin anions

MPS-Authors
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Schulz-Dobrick,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Jansen,  M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Schulz-Dobrick, M., & Jansen, M. (2006). Supramolecular intercluster compounds consisting of gold clusters and Keggin anions. European Journal of Inorganic Chemistry, 2006(22), 4498-4502.


Cite as: https://hdl.handle.net/21.11116/0000-000F-00FF-2
Abstract
Supramolecular intercluster compounds, that is, assemblies of
different, well-defined inorganic building blocks with diameters of > 1
nm, consisting of [Au-9(PPh3)(8)](3+) clusters and Keggin anions
[PW12O40](3-) were synthesized as single-crystals by a diffusion
method. Depending on the solvent combination, two modifications with
different core geometries of the gold cluster and different overall
packing type can be obtained as a single-phase in macroscopic amounts.
This approach leads toward the study of nanostructured matter with high
translational symmetry and the principles of nanoscopic self-assembly.