Synthesis and crystal structure determination of Cs([18]crown-6)Au·8NH3

Nuss, H.; Jansen, M.

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Synthesis and crystal structure determination of Cs([18]crown-6)Au·8NH₃

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Nuss, H.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Jansen, M.
Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Nuss, H., & Jansen, M. (2006). Synthesis and crystal structure determination of Cs([18]crown-6)Au·8NH₃. Zeitschrift für Naturforschung B, 61(10), 1205-1208.

Cite as: https://hdl.handle.net/21.11116/0000-000F-010D-2

Abstract

Cs([18]crown-6)Au center dot 8NH(3) was synthesized from CsAu and
[18]crown-6 in liquid ammonia. The extremely air- and
temperature-sensitive colorless, block-shaped crystals were analyzed by
single crystal X-ray diffractometry. The compound forms triclinic
crystals of space group P1 (no. 1) with a = 8.765(2), b = 11.186(2), c
= 13.997(3) angstrom, alpha = 86.180(6), beta = 89.669(6), gamma =
83.774(6)degrees, V = 1361.2(4) angstrom(3). The crystal structure
consists of ammonia nets extending perpendicular to [110] in which the
Cs([18]crown-6) fragments and the auride anions are embedded.