Crystal structure of Ni5P2

Oryshchyn, S.; Babizhetskyy, V.; Chykhriy, S.; Aksel'rud, L.; Stoyko, S.; Bauer, I.; Guérin, R.; Kuz'ma, Y.

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Crystal structure of Ni₅P₂

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Oryshchyn, S.
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Babizhetskyy, V.
Department Nanochemistry (Bettina V. Lotsch), Max Planck Institute for Solid State Research, Max Planck Society;
Department Quantum Materials (Hidenori Takagi), Max Planck Institute for Solid State Research, Max Planck Society;
Former Departments, Max Planck Institute for Solid State Research, Max Planck Society;

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Citation

Oryshchyn, S., Babizhetskyy, V., Chykhriy, S., Aksel'rud, L., Stoyko, S., Bauer, I., et al. (2004). Crystal structure of Ni₅P₂. Inorganic Materials, 40(4), 380-385.

Cite as: https://hdl.handle.net/21.11116/0000-000E-FEC2-9

Abstract

It is shown by x-ray diffraction, energy-dispersive x-ray spectrometry,
and electron probe microanalysis that, at 800degreesC, the Ni-P system
contains four phosphides in the composition range 25-33 at % P: Ni3P,
Ni5P2, Ni12P5, and Ni2P. The structure of Ni5P2 is determined by
single-crystal x-ray diffraction: sp. gr. P(3) over bar c1, new
structure type, a = 0.6613(3) nm, c = 1.2311(6) nm, 347 independent hkl
reflections with F-hkl > 4sigmaG(F-hkl), R-F = 0.0346. The key
structural features of Ni5P2 are discussed.